Place of Origin : Shanghai,China
Delivery Terms : In Stock, Within 2 Weeks; No Stock, Negotiatation.
Delivery Time : In Stock, Within 2 Weeks; No Stock, Negotiatation.
Product Capacity : 0.1kg-tons
Payment Terms : T.T 100% In Advance
2-Bromo-6-fluoroiodobenzene CAS 450412-29-0 1-Bromo-3-fluoro-2-iodobenzene 2-Iodo-3-Bromofluorobenzen
2-Bromo-6-fluoroiodobenzene CAS 450412-29-0 1-Bromo-3-fluoro-2-iodobenzene 2-Iodo-3-Bromofluorobenzen
Chemical Name: 2-Bromo-6-fluoroiodobenzene
Synonyms: 1-Bromo-3-fluoro-2-iodobenzene, 2-Iodo-3-Bromofluorobenzen
CAS No.: 450412-29-0
Molecular Formula: C6H3BrFI
Molecular Weight: 300.89
An Efficient Protocol For Synthesizing Dibenzodithiapentalenes
Two New Scalable Methods For The Synthesis Of Dibenzo[bc,fg]dithiapentalene (2) (DPP) Are Reported Starting From Either 1-bromo-3-fluoro-2-iodobenzene Over Four Steps In 57% Yield Or From THP-protected 3-fluorothiophenol Over Three Steps In 43% Yield. Attempts To Prepare Dibenzodioxapentalene (15) Using Similar Conditions Were Unsuccessful. Instead, We Observed The Formation Of A Macrocyclic Dimeric Product 16. Fluorine-hydrogen Bond Interactions Were Observed By NMR In The F/SH- And F/OH-substituted Dibenzothiophene And Dibenzofuran Intermediates.
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